1.
Chem Commun (Camb)
; 57(54): 6672-6675, 2021 Jul 06.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34132256
RESUMO
The base-promoted switchable synthesis of five- and six-membered cyclic carbamates using atmospheric pressure carbon dioxide as the C1 source was developed. The chemoselectivity of products was simply controlled by changing bases and solvents. The reaction proceeds effectively under mild conditions, affording valuable cyclic carbamates. Experimental results and DFT studies revealed the reaction mechanism.